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Barium Strontium Titanate

BST (Barium Strontium Titanate) is a multi-component single phase material with a Curie peak that can be moved by modifying the barium to strontium ratio. These different ratios allow a wide variation of properties for applications like:

  • Filled polymers
  • Microwave components
  • Implanted medical devices
  • Aerospace components
  • Standard capacitors

Curie temperature of Ferro BSTs with different BaXSr1-XTiO3 (from literature).

Processing Information for Fired Applications

Firing temperature 1340°C for 2 hours
Setter selection Zirconia
Composition Pb and Cd Free

Typical Physical Properties for Ba0.55Sr0.45TiO3

Particle Size (µm)
   D10 (Horiba)
   D50 (Horiba)
   D90 (Horiba)
0.66
1.44
3.81
Surface Area (m2/g) 1.87

These properties can be manipulated to make the powder coarser or finer depending on customer requirements. The (Ba/Sr)/Ti ratio can be fine tuned to offer optimum performance in the respective application as well.

Typical Electrical Properties for Ba0.55Sr0.45TiO3, based on Ferro fired disc measurements.

Dielectric Constant, K (@ 25°C, 1 kHz) 2367
DF (%) @ 1 kHz 0.19
DF (%) @ 1 MHz 0.09
Curie Point (°C) -15
K @ Curie Point 5717
DF 1 kHz @ Currie Point 0

Properties of experimental BST powders

Ba/Sr mole ratio Ba55/Sr45 Ba70/Sr30 Ba70/Sr30
(Ba+Sr)/Ti mole ratio 0.990 1.000 0.998
D10 (µm) 0.66 0.36 1.02
D50 (µm) 1.44 0.59 2.65
D90 (µm) 3.81 1.10 4.92
Surface Area (m2/g) 1.87 6.39 1.17
K @ 10% in PC 85 81 95
K dispersed in BST 1131 707 3499

The values shown for 10% dispersion in 90% propylenecarbonate (PC, K=64) are measured with a HP fluid cell and an Agilent 4284A impedance analyzer at 1 MHz. K of the dispersed particles is calculated accord-ing to the original Lichtenecker formula:

log K = v1logK1 + v2logK2

where v1 and v2 = PC and BST volume fractions and K1 and K2 = PC and BST K values.

BST shows promise in a number of applications, ranging from filled polymer to targeted fired medical applications. A number of advantages of this material are observed because it is a single phase material that offers properties beyond the mixing of various barium and strontium titanates. These translate into potential unique application areas especially for high frequency applications.